I am deciding what to do with my Frost Emblems in the future, and thought I should go ahead and just post my thought processes here so that they might possibly be of use to someone else.
Tier 10
These are definitely good buys for those emblems, and this is where all of mine have gone so far. I'm up to 3 pieces of Tier 10 now (though I can only really use 2 at a time), and my plan is to try to get the legs out of VoA for the 4 piece and save myself all those emblems.
Cloaks
Both the Emblem cloaks are quite nice, Scarlet Onslaught seems to be slightly better if you are expertise capped but Ocean Serpent is definitely a solid choice, and is a little more future-proof as well. I have the cloak from Gunship 25, so this one isn't really on my personal radar at all.
Chest/Gloves
These are pretty decent pieces, but since both are in Tier slots, I am not likely to be taking advantage of them anytime soon. Right now I am using 2 T9 and 2 T10 plus the crafted 245 chest, and there is no way I am paying 95 emblems to get 30 more strength and some extra ArPen. Gloves I am using for a Tier slot, and hopefully I will have the gloves from Festergut 25 for when I am ready to put Tier in the chest. Either way, these pieces are low priority.
Belt
The belt is quite nice if you need the hit, but I personally have way more than I want anyway, and the waist slot is one place I was hoping to be able to get rid of some. One of the bosses in Plagueworks drops a belt (Edit: which has hit and ends up being a sidegrade anyway), and Valithria 25 has the BiS, so with some luck I'll have the opportunity to get one of those pretty soon. Again, low priority.
Trinket
The Herkuml War Token isn't all that great of a trinket, and I am not really interested. On paper it actually ranks up there quite highly, despite the fact that the static bonus is haste. I used Fury of the Five Flights back in the day (and still do for some things, sadly) though, and I can tell you without hesitation that I hate the stacking AP mechanic. It's annoying to get to full stacks and in some fights you will lose the stack and have to start over again through no fault of your own. It hurts, because I could really, really use a trinket upgrade, but I don't think this is the way to go.
Libram
In a continuing theme, this is a nice upgrade, but way too minor to justify the expenditure of Emblems. For SoV, which is what you'll be using for most boss fights, its only a gain of 20 strength, one epic gem. For fights where you are using another seal, the benefit is quite a bit larger, but the stack is fairly slow building up (takes something like 45 seconds to pass Valiance when you are using SoV) and its just not a big enough gain to justify the cost.
That leaves us with...
Primordial Saronite
This seems to be just about the only thing that is left to buy with Frost Emblems. The attractiveness of this is highly dependent on a factor that is not really within my control, however. I am not particularly interested in either the crafted boots or legs (using legs as a tier slot, already have the 251 boots and would prefer the boots from Lady D 25 to the crafted) so the only thing I want Primordial Saronite for is Shadow's Edge. My guild still hasn't killed Rotface or Festergut, so we haven't actually decided who is getting the official support of the guild in obtaining the legendary. Since we are new, we don't have much of a history to draw on, so I don't envy the officers who have to make the choice. So far, however, only two people have put their names under consideration (including me). So...I don't really have anything to say, I guess, since I have no idea how this will go. If they pick me then I get some assistance in acquiring the Primordial Saronites, and that's where all my Emblems will start to go all of a sudden. If not, then who knows what'll happen. Maybe I can even scrounge up the 25 Saronite on my own and the guild can have 2 legendaries :)
So to summarize the gear available from the Frost Emblem vendors, Tier is awesome and everything else is a bit "meh." Obviously everything depends to some extent on your own personal gear, but as far as I can tell, none of the Emblem non-Tier pieces are going to be on a Best-in-Slot gear list. If you happen to be rocking a 200 belt and need some hit though, the Malevolent Girdle is right up your alley. As always with gear choices, you have to exercise those spreadsheet muscles and figure out what will work for you.
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